Robust testing of prototypes such as this hair dryer are one of the high-temperature applications well suited for ProtoTherm 12120. The photopolymer's thermal and moisture resistance are key properties needed to test the hair dryer in its working environment where hot, humid conditions are anticipated. Additionally, the resin's low coefficient of thermal expansion helps ensure the resin keeps a tight grip on the dryer's metal grill at elevated temperatures during testing.Stereolithography (SL) remains one of the most widely used ways of rapidly prototyping complex parts. SL can build prototypes with high accuracy and a wider range of physical and mechanical properties than selective laser sintering, laminated object manufacturing, 3D printing, and fused-deposition modeling.

Industry trends, however, are pushing the development of stronger, more durable SL resins good for more than just prototype formandfit evaluations. New SL grades are now going into parts for full functional testing, short production runs, and mass custom manufacturing, as well as for niche applications.

For rapid manufacturing, parts made from SL resins must be dimensionally accurate and have long-term durability. SL resin datasheets, however, highlight typical properties of recently built parts. Tests take place within a few days of part fabrication according to various standards. For most rapid-prototype applications, datasheets give enough information to gage how well the prototype will perform short-term. But for rapid production and mass custom-manufacturing purposes data-sheet information is often incomplete. It gives no indication as to how well the resin will perform over the product's expected life.

Recently, many commercial acrylate-epoxy hybrid or dual-curing photopolymers have begun being formulated with both free radical and cationic photoinitiators. During the SL build, these photopolymer resins form interpenetrating polymer networks (IPNs). The polymer networks and mechanical properties of the finished part evolve over time due predominantly to the dark reactions of epoxies. Furthermore, water absorbed from the environment often affects the acid-catalyzed cationic curing. This can cause dimensions and properties to change over time. As a result, the finished part may become fragile in weeks or months, making it unsuitable for production.

Effect of postcuring and aging under different conditions at room temperature for up to 66 weeks on the tensile strength of Prototherm 12120 parts.There was a recent 66-week investigation on how aging affects SL parts made from an acrylate-epoxy hybrid resin. The study helps shed light on how these cross-linked IPN systems stand up to thermal and mechanical stress over the long haul. It evaluated how the tensile properties of the ProtoTherm 12120 photopolymer changed under a variety of scenarios as well as the amount of water it absorbed at ambient conditions.

EFFECTS OF AGING ON TENSILE PROPERTIES
One group of UV-postcured ProtoTherm 12120 samples were held at ambient while another (UV plus thermally postcured) saw 100% RH for up to 66 weeks. The Young's modulus and tensile strength of UVpostcured parts rose slowly over time, making the aged parts very rigid and strong. Meanwhile, the elongation at break trended higher initially and then fell somewhat to about 2 to 3% on average after aging at ambient for 66 weeks. The results indicate that aged parts may give a high modulus and tensile strength, thus letting the SL materials serve as a replacement for some unfilled, clear production grade polymers. Next, the aged, UV-postcured samples were thermally cycled to 160°C for 2 hr one day before testing. Both the tensile modulus and strength of the samples fell into a relatively narrow range regardless of how they had been aged. Tensile properties of samples compared to a similar group that was subsequently aged at ambient showed that the 160°C postcuring nearly eradicated the effects of aging.

Effect of postcuring and aging under different conditions at room temperature for up to 66 weeks on the tensile elongation of Prototherm 12120 parts.Furthermore, thermally postcured samples maintained essentially the same modulus and strength over time. Aging in ambient had little effect on tensile properties. The above results confirmed an earlier theory that the properties of fully cured acrylate-epoxy IPNs should not change during use. Thermal analysis revealed that 160°C heattreated parts saw no further thermally induced, exothermic polymerization. Such parts would remain dimensionally stable despite long-term aging. In contrast, thermal treatment at about 80°C (up to 24 hr) produced different results on SL parts made from another commercial resin. These parts did not completely cure. This likely would lead to further part brittleness with aging.

Aging for 66 weeks in 100% humidity at room temperature barely degraded the tensile properties of another group of UV and thermally postcured parts. The Young's modulus and tensile strength of the initially UV and thermallypostcured parts dropped slightly after 66 weeks in 100% RH. Elongation-at-break rose slightly. Water may act as a plasticizer that reduces the interactions of polymer chains and allows for greater extension.

WATER ABSORPTION
Researchers watched how the various postcured samples absorbed water at room temperature for up to one year. The water uptake of the ProtoTherm 12120 material was extremely low. The UV and thermally postcured samples had slightly lower water absorption than those UV postcured.

The bound water was likely responsible for the slight drop in tensile modulus and higher elongation for the aged, wet samples. These effects are due to how water plasticizes the IPN matrix. The absorbed water, surprisingly, did not embrittle the parts as they aged, indicating good resistance of the fully cured material to hydrolytic breakdown of the polymer networks.

All in all, the long-term results were good. These along with high build accuracy, fast photo speed, and insensitivity to moisture makes the Proto-Therm 12120 photopolymer a prime candidate for rapid prototyping and functional testing at elevated temperature and high humidity. And its outstanding resistance to aging without deterioration in mechanical strength makes it suitable for rapid production applications.

Postcure and conditioning at room temperature of test samples

Sample
code

UV
postcure

Thermal postcure
before aging

66-week
aging condition

Thermal postcure
after aging

12120A

Yes

No

Ambient

No

12120B

Yes

No

Ambient

Yes

12120C

Yes

Yes

Ambient

No

12120D

Yes

Yes

100% RH

No

 

SAMPLE PREP

ProtoTherm 12120 is a general-purpose photopolymer that resists high temperatures. Researchers built test samples using an SLA 7000 System from 3D Systems, Valencia, Calif., equipped with a solid-state frequency tripled Nd:YV04 laser emitting at 354.7 nm. The photopolymer is optimized for lasers with this wavelength and has a critical exposure (Ec) of 11.8 mJ/cm2 and a depth of penetration (Dp) of 150 m. Parts were prepared by irradiating a 150- m thick layer of liquid resin with 62.5 mJ/cm2 (E10) of energy.

Water absorption of Prototherm 12120 parts after UV postcure or UV plus thermal postcure at room temperature for up to one year.An E10 exposure is enough to polymerize the resin and assure good adhesion to the previously coated and exposed layer. The samples were cleaned with tripropylene glycol monomethyl ether (TPM) and isopropanol and then postcured for 60 min in a 3D Systems PCA with 10 Phillips TLK/05 40-W bulbs. Some of the UV-postcured samples also were given a 160°C thermal postcure for 2 hr with ramps of 1°C/min from room temperature. This produced a number of test parts for various conditioning and test runs.

The tensile tests on aged bars take place at predetermined time intervals in accordance with ASTM D638 — barring no control of test-room temperature and humidity. Test bars also saw no two-day equilibration period after aging and before testing. Reported tensile test results were the average of five measurements.

UV and UV plus thermally postcured cylindrical specimens (four each; 50.7 mm in diameter and 6.3 mm in thickness), were first oven dried at 50°C for 24 hr or 110°C for 1 hr then soaked in distilled water at room temperature. Specimens were patted dry and weighed at various time intervals to determine water uptake.

 

MAKE CONTACT

DSM Desotech, Somos Div. • (302) 326-8112 • dsmsomos.com

3D Systems • (661) 295-5600 • 3dsystems.com